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Jump starting a Mercedes E350 is similar to jumping any other vehicle. You'll need jumper cables and a second vehicle or a jump box if another vehicle is not available. Begin by opening the hood and connecting the positive cable clamp to the positive jump terminal in the Mercedes. Then, connect the positive cable to the positive battery terminal in the working car. Connect the negative cable to the grounding point in the Mercedes and the negative to the negative battery terminal in the working car. Start the engine in the working car and let it run for a minute or two before attempting to start the Mercedes engine.
Here's an alternative: "Guide for Jump Starting a Dead Battery on an A350E Class Vehicle
To start a Mercedes E350 by jumping it, connect the cables to the positive and negative terminals of the working battery first, then attach them to the corresponding points under the hood of the car that needs a jump.